Home Chemistry Heterocyclic Building Blocks Carbazole Series 9-([1,1'-Biphenyl]-4-Yl)-9H-Carbazole
Halogenation: The biphenyl moiety in 9-([1,1'-biphenyl]-4-yl)-9H-carbazole contains carbon-carbon double bonds which can undergo halogenation reactions, such as bromination or chlorination.
Nucleophilic Substitution: If there are suitable leaving groups attached to the molecule, nucleophilic substitution reactions may occur. The reaction can proceed via either an SN1 or SN2 mechanism, depending on the nature of the substrate and the nucleophile.
Reduction: The carbazole core may undergo reduction reactions to form dihydrocarbazole or tetrahydrocarbazole derivatives. This can be achieved using reducing agents like lithium aluminum hydride (LiAlH4) or catalytic hydrogenation.
Oxidation: The compound can potentially be oxidized, particularly if there are electron-rich sites available for oxidation. This could lead to the formation of various oxidation products.
Cross-Coupling Reactions: Given the presence of the biphenyl group, cross-coupling reactions with suitable partners (e.g., aryl halides) in the presence of a transition metal catalyst may be possible. Common examples include Suzuki, Heck, or Stille couplings.
Grignard Reactions: The compound may react with a Grignard reagent, which is an organomagnesium compound. This can lead to the formation of a new carbon-carbon bond.
Friedel-Crafts Alkylation or Acylation: If conditions are right, the aromatic rings in the molecule can undergo Friedel-Crafts reactions with alkyl or acyl halides in the presence of a Lewis acid catalyst.
Amination: The compound can potentially undergo amination reactions, where an amino group is introduced. This could be achieved through various methods, such as using ammonia or amine nucleophiles.
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9-([1,1'-Biphenyl]-4-yl)-2-bromo-9H-carbazole
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(4'-(9H-Carbazol-9-yl)-[1,1'-biphenyl]-4-yl)boronic acid
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(9-([1,1'-Biphenyl]-4-yl)-9H-carbazol-3-yl)boronic acid
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Boronic acid, b-(9-[1,1'-biphenyl]-4-yl-9h-carbazol-2-yl)-
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9-(4'-Bromo-[1,1'-biphenyl]-4-yl)-9H-carbazole
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9-([1,1'-Biphenyl]-4-yl)-3-bromo-9H-carbazole
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2-(4'-(9H-Carbazol-9-yl)-[1,1'-biphenyl]-4-yl)acetonitrile
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